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wine explorer /desktop=civ4,1280x800 Civ4BeyondSword.exe
If I use 1280x799 resolution instead, it starts up on the monitor from which I run the command, which is expected behaviour (but messes up my screen resolutions).
I'm running 64-bit, wine's in a 32-bit chroot. Arch Linux, Gnome DE. Same results with or without compiz. Obviously running an nVidia card. Some indications on what I should look into would be appreciated.